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2 article(s) from Kubicki, Maciej

New aryloxybenzylidene ruthenium chelates – synthesis, reactivity and catalytic performance in ROMP

Patrycja Żak,
Szymon Rogalski,
Mariusz Majchrzak,
Maciej Kubicki and
Cezary Pietraszuk

Beilstein J. Org. Chem. 2015, 11, 1910–1916, doi:10.3762/bjoc.11.206

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Figure 1: Coordination motif of latent catalyst of olefin metathesis in which alkylidene ligand is bound to t...

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Figure 2: Known latent catalysts of olefin metathesis in which alkylidene ligands are bound to a heteroatom, ...

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Figure 3: Selected, known aryloxybenzylidene chelates [9,10].

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Scheme 1: Synthesis of catalyst precursors 4–6 [11].

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Scheme 2: Synthesis of catalysts 8–10.

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Scheme 3: Synthesis of catalysts 13 and 14.

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Figure 4: ROMP of COD. Conditions: CH₂Cl₂, 40 °C, 0.5 M, [COD]:[Ru] = 20000; For clarity, only two representa...

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Figure 5: ROMP of cod. Conditions: CH₂Cl₂, 40 °C, 0.5 M, [cod]:[Ru] = 20000; For clarity only representative ...

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Scheme 4: ROMP of monomer 15.

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Figure 6: ROMP of monomer 15. Conditions: CDCl₃, 40 °C, 0.08 M, [15]:[Ru] = 200.

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Figure 7: ROMP of monomer 15. Conditions: CDCl₃, 23 °C, 0.08 M, [15]:[Ru] = 200.

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Scheme 5: Formation of phosphine free dimeric complex in the presence of CuCl.

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Figure 8: A perspective view of complex 16, the ellipsoids are drawn at the 50% probability level. Hydrogen a...

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Scheme 6: Synthesis of complexes 1a and 8 starting from dimer 16.

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Scheme 7: Activation of complex 8 with one equivalent of HCl.

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Published 14 Oct 2015

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Molecular recognition. 1. Crystal structures of hexaazamacrocyclic amines containing p-xylylene spacers and their adducts with acids

Teresa Borowiak,
Grzegorz Dutkiewicz,
Maciej Kubicki,
Marek Pietraszkiewicz,
Agnieszka Gil and
Rainer Mattes

Beilstein J. Org. Chem. 2005, 1, No. 16, doi:10.1186/1860-5397-1-16

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Scheme 1: Formulas of macrocyclic amines, 1: 1,5,9,18,22,26-hexaaza [11.11]-p-cyclophane and 2: 1,4,7,16,19,2...

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Figure 1: The ionic synthon of 1-FUM built from one macrocyclic hexa-protonated cation and six fumaric anions...

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Figure 2: The structure of one sheet in 1-FUM – a projection perpendicular to the phenyl ring planes. Tapes o...

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Figure 3: The arrangement of two sheets (after rotation by 90°). The height of one sheet corresponds to the h...

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Figure 4: The molecular conformation of 1-N-Me, atom labeling scheme indicated. Displacement parameters are d...

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Figure 5: The unit cell of 1-N-Me, stacks of molecules are indicated.

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Published 09 Dec 2005

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